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Coal-fired boilers are mainly operated at either subcritical or supercritical conditions. From a thermo-physics perspective, two phase mixtures of water and steam are replaced by a single supercritical fluid when the boiler pressure increases above the critical pressure of 22.12 MPa and the corresponding saturation temperature of 374 °C (Shen and Cheng, 2004).

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Reduction Efficiency for Various Utility Boiler Sizes [2] Figure 1.1b: SNCR NO x Reduction Efficiency for Boilers in Various Industry Sectors [2] 0 10 20 30 40 50 60 70 0 100 200 300 400 500 600 700 800) Boiler size (MW) SNCR Reductions for Utility Boilers Coal-fired Boilers 0 20 40 60 80 100 0 200 400 600 800 1000) Boiler size (MMBtu/hr)

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